Friday, March 31, 2017

New Developments March 2017

Research advances energy savings for oil, gas industries A Washington State University research team has improved an important catalytic reaction commonly used in the oil and gas industries. The innovation could lead to dramatic energy savings and reduced pollution. Methane also is a primary ingredient in natural gas used to heat homes, and it can be converted into many useful products including electricity. But breaking the strong bond between its carbon and hydrogen takes a tremendous amount of energy. To convert methane, the oil and gas industry most often uses a nickel-based catalyst. But it is often less expensive to simply burn the methane in giant flares on site; however, this adds greenhouse gases to the atmosphere, contributing to global warming, and wastes energy. In the U.S., for example, the amount of methane burned annually is as much as 25 percent of the country's natural gas consumption. The researchers determined that they can dramatically reduce the energy needed to break the bond between carbon and hydrogen by adding a tiny bit of carbon within the nickel-based catalyst. This creates nickel carbide, which generates a positive electrical field. This novel catalyst weakens the methane molecule's hydrogen-carbon bond, allowing it to break at much lower temperatures.

A city’s solar potential depends on the length of its road network This is because the formation of the road network defines the spaces that can be filled by buildings. And the resulting arrangement of buildings influences the amount of sunlight each building receives.



This non-toxic battery lasts a decade, could be renewable energy’s missing piece Researchers at Harvard University have developed a new kind of low-cost battery that can run for more than 10 years with no maintenance. It is also non-toxic and inexpensive, to boot. Instead of the solid electrodes found in conventional batteries, flow batteries contain liquid electrolytes held in separate tanks that react as they flow through cells. Today’s flow batteries use electrolyte solutions of vanadium metal dissolved in corrosive acids. Not only is vanadium expensive, but this formulation also adds cost because it requires special corrosion-resisting tanks. Plus, all of today’s battery technologies start losing their capacity to hold charge after a few years, or a few hundred recharge cycles. The battery loses only 1 percent of its capacity after over 1,000 charge cycles, which is much longer than lithium batteries. The researchers also calculated that if the battery was charged and discharged completely once a day, “we would expect it to retain 50 percent of its energy storage capacity after 5,000 cycles, or about 14 years.”

Tweaking electrolyte makes better lithium-metal batteries The additive enabled a 4.3-volt battery that retained more than 97 percent of its initial charge after 500 repeated charges and discharges, while carrying 1.75 milliAmps of electrical current per square centimeter of area. It took the battery about one hour to fully charge.

New approach to improving lithium-sulfur batteries Researchers have demonstrated a new polysulfide entrapping strategy that greatly improves the cycle stability of Li-S batteries. Rechargeable lithium-ion batteries are the power behind most modern portable electronics, including cell phones, tablets, laptops, fitness trackers, and smart watches. However, their energy density -- that is, the amount of energy stored within a given amount of physical space, or mass -- will need to be improved for these batteries to see widespread use in smart grid and electric transport applications. the energy density of lithium-sulfur (Li-S) batteries is five times higher than that of Li-ion batteries. That advantage, combined with low cost, suggests that this alternative technology shows promise for high-energy storage applications. But the use of Li-S batteries is limited by a different problem: rapid capacity fade, which means that the amount of charge these batteries can deliver at the rated voltage decreases significantly with use. Wei and colleagues have demonstrated a new polysulfide entrapping strategy that greatly improves the cycle stability of Li-S batteries.

Electronic energy meters' false readings almost six times higher than actual energy consumption Some electronic energy meters can give false readings that are up to 582% higher than actual energy consumption. The author of a new report estimates that potentially inaccurate meters have been installed in the meter cabinets of at least 750,000 Dutch households.

Vertical wind turbines could produce 10x the power per acre as their horizontal counterparts  vertical-axis wind turbines (VAWTs), which are cylindrical and typically look like an egg-beater or a weather vane. Vertical-axis turbines are cheaper to make and maintain, take up less space, and safer for birds and bats. The problem is that they are not very efficient. The power output of a wind farm depends on how its turbines are arranged. That’s because individual turbines interact with each other and affect the flow of wind across the array. When conventional wind turbines are placed close to each other, for instance, upstream turbines slow down wind and cause turbulence, which decreases power output from neighboring turbines. This is why such turbines have to be placed hundreds of feet apart. VAWTs, on the other hand, affect each other positively when placed close to each other.

Lithium-ion battery inventor introduces new technology for fast-charging, noncombustible batteries A team of engineers led by 94-year-old John Goodenough, professor in the Cockrell School of Engineering at The University of Texas at Austin and co-inventor of the lithium-ion battery, has developed the first all-solid-state battery cells that could lead to safer, faster-charging, longer-lasting rechargeable batteries for handheld mobile devices, electric cars and stationary energy storage. The UT Austin battery formulation also allows for a greater number of charging and discharging cycles, which equates to longer-lasting batteries, as well as a faster rate of recharge (minutes rather than hours). Instead of liquid electrolytes, the researchers rely on glass electrolytes that enable the use of an alkali-metal anode without the formation of dendrites. This is the first all-solid-state battery cell that can operate under 60 degree Celsius.

Sustainable, high energy density battery created It is based on manganese dioxide (MnO2), an abundant, safe and non-toxic material. The battery is intended for use at the scale of the power grid. This would make widespread use of solar and wind power possible.

Chemists create molecular 'leaf' that collects and stores solar power without solar panels a molecule that uses light or electricity to convert the greenhouse gas carbon dioxide into carbon monoxide -- a carbon-neutral fuel source -- more efficiently than any other method of "carbon reduction." Burning fuel -- such as carbon monoxide -- produces carbon dioxide and releases energy. Turning carbon dioxide back into fuel requires at least the same amount of energy. The molecule -- a nanographene-rhenium complex connected via an organic compound known as bipyridine -- triggers a highly efficient reaction that converts carbon dioxide to carbon monoxide.The ability to efficiently and exclusively create carbon monoxide is significant due to the molecule's versatility. "Carbon monoxide is an important raw material in a lot of industrial processes," Li said. "It's also a way to store energy as a carbon-neutral fuel since you're not putting any more carbon back into the atmosphere than you already removed. You're simply re-releasing the solar power you used to make it." The molecule developed at IU takes advantage of the light-absorbing power of nanographene to create a reaction that uses sunlight in the wavelength up to 600 nanometers -- a large portion of the visible light spectrum. If thorium reactors are so great, what's the holdup? It basically boils down to this: "The science is easy. The engineering is hard." LFTR's molten salt contains beryllium to help regulate nuclear fission, but it's a big health hazard. If there's ever a leak or spill of the material, Petti says it solidifies into a crumbly 'snow' that workers might inhale, raising their risk of a lung cancer and a disease called berylliosis. Molten salt also contains lithium, which a reactor can breed into a radioactive gas called tritium. It's less of a threat than beryllium, but it can bond to water and make it slightly radioactive, possibly leading to cancer and birth defects. "Salts can be very harmful to metal piping (think of salt used on the road and what it does to car bodies)," Swank wrote.
"Another challenge is the use of [fluorine] which is highly toxic due to its strong ability to strip electrons." Petti said the LFTR's big bugaboo is its proliferation risk, since U-233 fuel could be used to make a nuclear weapon. ”If they want that, they need to be talking to their elected officials and demanding it, in fact, and saying 'we want to see these things happen.' Because only a society that decides to embrace this kind of technology is going to ultimately realise its benefits."

A Forgotten War Tech Could Safely Power Earth for Millions of Years Energy from fusion is promising, but it's not yet proved to work, let alone on a commercial and competitive scale. Nuclear reactors, on the other hand, fit the bill: they're dense, reliable, emit no carbon, and - contrary to bitter popular sentiment - are among the safest energy sources on Earth. Called a molten-salt reactor, the technology was conceived during the Cold War and forgoes solid nuclear fuel for a liquid one, which it can "burn" with far greater efficiency than any power technology in existence. It also generates a small fraction of the radioactive waste that today's commercial reactors - which all rely on solid fuel - do. And, in theory, molten-salt reactors can never melt down. What's more, feeding a molten-salt reactor a radioactive waste from mining, called thorium (which is three to four times more abundant than uranium), can 'breed' as much nuclear fuel as it burns up. A dysfunctional uranium fuel cycle in the US has not helped, where just 3 to 6.5 percent of solid uranium fuel is burned up - and the remaining 93 to 97 percent is treated as radioactive waste and not reprocessed and recycled. That maximum death-toll estimates from that analysis show:
  • Natural gas is 1.3 times as dangerous as nuclear
  • Coal is 27 times as dangerous as nuclear
  • Hydroelectric is 46 times as dangerous as nuclear
In absolute terms, nuclear energy prevents about 80,000 air-pollution-related deaths a year, according to a 2013 study. One of the most important things about a nuclear fuel is the chance its nucleus will react with a flying neutron, a property called neutron cross section. What happens in a thorium reactor is thorium absorbs neutrons and it forms a new fuel - uranium-233 - that can then sustain the reaction," he said. "It can produce enough neutrons to continue turning more thorium into U-233. Breeding U-233 from thorium also created significant amounts of a worrisome contaminant called U-232, which scientists had not yet figured out how to remove. U-232 emits a lot of alpha radiation, which can trigger spontaneous fission - not good for a nuclear weapon you don't want to randomly explode. Its decay products also emit a lot of gamma radiation, which can wreck electronics and harm or kill people who handle bombs. In addition, gamma rays can blow a bomb's cover, since they are detectable by aeroplane or satellite, and pass through all but the heaviest radiation shielding. Scientists like Seaborg weren't even certain a U-233-powered bomb would blow up very well.

New nanofiber marks important step in next generation battery development Materials researchers at Georgia Institute of Technology have created a nanofiber that could help enable the next generation of rechargeable batteries and increase the efficiency of hydrogen production from water electrolysis. During the synthetization process, the researchers used a technique called composition tuning -- or "co-doping" -- to improve the intrinsic activity of the catalyst by approximately 4.7 times. The perovskite oxide fiber made during the electrospinning process was about 20 nanometers in diameter -- which thus far is the thinnest diameter reported for electrospun perovskite oxide nanofibers. The researchers found that the new substance showed markedly enhanced oxygen evolution reaction capability when compared to existing catalysts. The new nanofiber's mass-normalized catalytic activity improved about 72 times greater than the initial powder catalyst, and 2.5 times greater than iridium oxide, which is considered a state of the art catalyst by current standards.

EnergyTrend: Cylindrical and Polymer Lithium Battery Cell Price Generally Increase in 1H17 The energy density development for cylindrical batteries has stopped. Cylindrical battery makers will focus more on larger size product development to fulfill the need for new vehicle applications. Fewer cylindrical batteries will be used in laptop application, therefore despite the increasing cylindrical battery capacity, more and more cylindrical batteries are now used in power application.

India to Overtake Japan as the World’s Third Largest Solar Market in 2017, Expects EnergyTrend “While China remains the largest regional market, its domestic PV installation target for this year is slightly lower than last year’s according to the latest government announcement,” said EnergyTrend analyst Celeste Tsai. “As for the second-place U.S., the country’s current political climate is not conducive to the growth of its PV market. At the same time, Japan will continue to lower its feed-in tariff rates over the next few years. Because India still maintain strong demand for PV products, it has the potential to overtake Japan to become the world’s third largest solar market by taking at least 14% of the year’s total PV demand.”

Wind energy is tough on bats—but it doesn’t have to be that way Though concern about wind energy’s environmental impacts has focused mostly on birds, turbine blades also kill vast numbers of bats—hundreds of thousands every year, raising “the possibility for near or total extinction from wind-energy-related fatalities,” say researchers who projected current mortality rates into the future. Frick and colleagues calculate that hoary bats need population growth rates of between 6 and 14 percent to keep pace with turbine deaths. The actual population growth rate of that long-lived, slow-reproducing species is around 1 percent. Even in an “optimistic” scenario, writes Frick’s team, hoary bat populations will fall by 50 percent in the next half-century. A more realistic figure is 90 percent. Bats are most active when winds are slow and temperatures mild: below about 13 miles per hour and above 49 degrees Fahrenheit, respectively. Martin’s team adjusted the settings accordingly on half of Sheffield’s 16 towers, raising the cut-in speed—the wind speed at which generators give turbines a boost to get them going—to 6mph from 4mph on nights warm enough for bats to fly. A next question to answer, then, might be how people already know so much about solving the problem, yet do so little.

How much waterdoes it take to makea cup of tea? So how much water goes into a cup of tea? Somewhere around 30 litres of water is required for tea itself, 10 litres for a small dash of milk and a further 6 litres for each teaspoon of sugar. This means that a simple cup of tea with milk and two sugars could actually require 52 litres of water – enough to fill my kettle more than 30 times. The water needed to grow the tea leaves and the sugar cane, as well as growing the feedstock consumed by dairy cows; the water used in the manufacturing process for both the main products and their packaging; the water used to brew the tea and clean the dirty cup; not to mention a number of other things such as the water used to generate the energy to boil the kettle. According to the latest figures from the UN, if we continue our on current trajectory then by 2050 water demand is projected to grow by 55 percent. Using large volumes of freshwater somewhere like the north of China, a region facing serious water
shortages and major issues with pollution, is a far greater issue than using it somewhere like Canada, which has 20 percent of the world’s freshwater supply.

Pressed, not baked: A green recipe for making tiles and bricks Ceramic materials such as bricks, porcelain tiles, and cement carry a heavy carbon emissions burden. Manufacturing them requires burning large amounts of fossil fuels to fire raw materials in kilns at temperatures above 1,400°C. Swiss researchers have now developed a new way to manufacture ceramics that skips the heating altogether. Instead, the researchers make ceramics by adding water to the raw material and compressing it at room temperature. The method, outlined in the journal Nature Communications, slashes energy consumption and emissions, and produces a material that’s stronger than concrete. Ceramics are non-metal crystalline materials used in everything from building materials and dinnerware to medical implant coatings and aerospace parts. Today, manufacturing Portland cement alone results in 5 percent of the world’s total carbon emissions. The researchers started with an extremely fine calcium carbonate nanopowder. They added water and then compacted the material in a conventional hydraulic press at room temperature. The new process, which is called cold-sintering, could be made carbon-negative by capturing carbon from the atmosphere to produce the carbonate nanopowder.

Environmentally friendly, almost electricity-free solar cooling This absorption chiller works in the same way as the gas refrigerators used in Finnish holiday cabins, for example. But in this case, a solar thermal collector is used instead of gas. The method requires electricity for the flow pumps only. If necessary, the chiller can also serve as a heat pump. If the collectors did not produce enough energy during, say, the winter, or on a cloudy day, a heat pump served as a substitute energy source. Other possible energy sources would be district heating, biofuel boilers or industrial process heat.

Scientists harness solar power to produce clean hydrogen from biomass Lignocellulose is the main component of plant biomass and up to now its conversion into hydrogen has only been achieved through a gasification process which uses high temperatures to decompose it fully. The new technology relies on a simple photocatalytic conversion process. Catalytic nanoparticles are added to alkaline water in which the biomass is suspended. This is then placed in front of a light in the lab which mimics solar light. The solution is ideal for absorbing this light and converting the biomass into gaseous hydrogen which can then be collected from the headspace. The hydrogen is free of fuel-cell inhibitors, such as carbon monoxide, which allows it to be used for power. The nanoparticle is able to absorb energy from solar light and use it to undertake complex chemical reactions. In this case, it rearranges the atoms in the water and biomass to form hydrogen fuel and other organic chemicals, such as formic acid and carbonate.

New materials could turn water into the fuel of the future Solar fuels, a dream of clean-energy research, are created using only sunlight, water, and carbon dioxide (CO2). Researchers are exploring a range of target fuels, from hydrogen gas to liquid hydrocarbons, and producing any of these fuels involves splitting water. To create practical solar fuels, scientists have been trying to develop low-cost and efficient materials, known as photoanodes, that are capable of splitting water using visible light as an energy source. Over the past four decades, researchers identified only 16 of these photoanode materials. Now, using a new high-throughput method of identifying new materials, a team of researchers led by Caltech's John Gregoire and Berkeley Lab's Jeffrey Neaton and Qimin Yan have found 12 promising new photoanodes. In the work described in the PNAS paper, they explored 174 metal vanadates -- compounds containing the elements vanadium and oxygen along with one other element from the periodic table.

From space to the streets: New battery model also makes electric cars more reliable They are able to predict how much the on-board battery will in fact be utilized in the course of the satellite's mission. The efficiency achieved here is about five times greater than with conventional systems. And electric cars on Earth are already benefiting from the procedure as well.

Mapping the effects of crystal defects New research offers insights into how crystal dislocations -- a common type of defect in materials -- can affect electrical and heat transport through crystals, at a microscopic, quantum mechanical level. The findings could affect the search for better thermoelectric materials, which can convert heat to electricity. These are used for generating power from waste heat, or providing heaters for car seats. Thermoelectric systems can also provide cooling, for cold-drink chests, for example.

Liquid fuel for future computers In the future, a new type of tiny redox flow battery will supply tightly packed electronic components with energy, while also dissipating the heat they produce. As the scientists use two liquids that are known to be suitable both as flow-battery electrolytes and as a medium to also effect cooling, excess heat can also be dissipated from the chip stack via the same circuit. The battery built by the scientists is only around 1.5 millimetres thick. The idea would be to assemble chip stacks layer by layer: a computer chip, then a thin battery micro-cell that supplies the chip with electricity and cools it, followed by the next computer chip and so on. The output of the new micro-battery also reaches a record-high in terms of its size: 1.4 watts per square centimetre of battery surface. Even if you subtract the power required to pump the liquid electrolytes to the battery, the resulting net power density is still 1 watt per square centimetre. Although the power density of the new micro-flow battery is very high, the electricity produced is still not entirely sufficient to operate a computer chip. In order for the flow battery to be used in a chip stack, it must be further optimised by industry partners.

Enzyme function inhibits battery aging, researchers show It has been known in biology for a long time that the excited oxygen molecule singlet oxygen is the main cause of aging in cells. To counter this, nature uses an enzyme called superoxide dismutase to eliminate superoxide as a free radical. Superoxide also occurs in cell respiration for energy production and is the preliminary stage and thus source of singlet oxygen. A study has now stumbled upon astonishing parallels of oxygen chemistry in battery systems. On top of the problem recognition and methodology development, the article in Nature Energy also provides an initial approach to how the storage cell can protect itself from the reactive oxygen species. "In essence, the battery needs the function of the enzyme superoxide dismutase. We were able to identify a class of molecules which can fulfil this function. There has to be a suitable way of getting the "enzyme" into the battery system -- either through the electrolyte itself or by means of an additive which dissolves in the electrolyte.

Liquid storage of solar energy: More effective than ever before The stored energy can be transported and then released as heat whenever needed. It is possible to convert the solar energy directly into energy stored in the bonds of a chemical fluid -- a so-called molecular solar thermal system. The liquid chemical makes it possible to store and transport the stored solar energy and release it on demand, with full recovery of the storage medium. The process is based on the organic compound norbornadiene that upon exposure to light converts into quadricyclane.

Energy: Most efficient silicon solar cells yet The cell achieves a certified conversion efficiency of 26.3%, showing that silicon solar cells are more efficient than ever and suggesting that more efficient silicon solar panels are on the way.

Self-sustaining bacteria-fueled power cell created Researchers have developed the next step in microbial fuel cells (MFCs) with the first micro-scale self-sustaining cell, which generated power for 13 straight days through symbiotic interactions of two types of bacteria. In a cell chamber about one-fifth the size of a teaspoon -- 90 microliters -- researchers placed a mixed culture of phototrophic and heterotrophic bacteria. Those metabolic processes generated an electrical current -- 8 microamps per square centimeter of cell -- for 13 straight days. A common 42" high-definition television takes about half an amp of electrical current to function which would, theoretically, require roughly 62,500 cells from the experiment. In reality, these cells will be used to provide power in remote or dangerous locations for low-power items like health monitors and infrastructure diagnostic sensors. Last spring, researchers connected nine biological-solar (bio-solar) cells into a working bio-solar panel for the first time ever. The bacteria used in that experiment were phototrophic. That panel generated the most wattage of any existing small-scale bio-solar cells: 5.59 microwatts. Choi has also developed an origami-inspired microbe-based paper battery, a microbe-based battery that can use human saliva as a power source, a battery that can be printed on paper and battery designs inspired by Japanese ninja throwing stars.

Promising results obtained with a new electrocatalyst that reduces the need for platinum A group researchers has developed a manufacturing method for electrocatalysts that only uses one hundredth of the amount of platinum generally used in commercial products. The activity achieved using the new material is similar to that of commercial electrocatalysts. The method is based on the special characteristics of carbon nanotubes.

The economic case for wind, solar energy in Africa To meet skyrocketing demand for electricity, African countries may have to triple their energy output by 2030. While hydropower and fossil fuel power plants are favored approaches in some quarters, a new assessment has found that wind and solar can be economically and environmentally competitive options and can contribute significantly to the rising demand. The tool they used to make these evaluations, the Multicriteria Analysis for Planning Renewable Energy (MapRE, at mapre.lbl.gov) was developed at Berkeley Lab in collaboration with IRENA and is open-source and publicly available to researchers and policymakers.


Air could be the world's next battery surplus energy generated by wind turbines and solar cells is used to compress air, which is stored in caverns in solid bedrock. When air is compressed, it heats up, so a separate underground heat store stockpiles the heat generated by the compression process. When the energy is needed, the air is released through a gas turbine, which generates electricity. The more hot air that is released through the heat store on its way out, the more electricity will be generated; in other words: the more effective is the energy storage. The two largest compressed air stores in the world are in Germany and the USA. They are underground chambers created in salt formations. But these plants lose a large proportion of the potential energy of the compressed air, because they do not incorporate a system to store the heat produced during the air compression stage. it is estimated that this technology could raise the efficiency of the system to as much as 70-80%. The corresponding figures for most of the existing storage sites are no better than 45 to 55 per cent, which means that the produced energy is only half of what was initially used to compress the air into the cavern. there is only a single requirement as regards the choice of site. Large hollow spaces must already exist, as it would be too expensive to excavate new caverns and make them safe.

Compact, efficient system stores solar energy in liquids Now, Swedish researchers report an efficient, compact new way to store solar energy in chemical liquids. They have made a prototype hybrid device with two parts. One stores solar energy in the chemical bonds of a molecule; the stored energy can then be released as heat whenever needed. The other part uses sunlight to heat up water, which can be used immediately. The device stores 1.1 percent of the sunlight hitting it as chemical energy, which is a 100-fold improvement over the system the researchers first developed in 2013. Up to 80 percent of sunlight goes to heat the water. The device could store and then release energy more than 100 times with almost no decrease in efficiency. They also want to develop a solvent-free system: the chemical solution currently uses a toluene solvent which could be toxic.

Low-carbon energy boosts human and ecological health Replacing coal and gas electricity generation with solar, wind, hydro, and nuclear power would have substantial benefits for both human and ecological health. Even setting aside climate change, the impact on human health of air pollution, radiation, carcinogens, and other toxins is smaller from alternative energy sources compared to fossil fuels. The picture is similar for ecosystem health, which the researchers measured by calculating the fraction of current species that could go extinct as a result of a particular anthropogenic change to the environment. Solar, wind, hydro, and nuclear power all have very low environmental impacts, they found. An unexpected finding of the study, however, is that biomass fuels have a surprisingly large environmental impact. This is mostly because it takes a lot of space to grow the plants that are then turned into biofuels. The use of herbicides on biofuel plantations also contributes to the environmental impact of this form of energy.

Chevy’s Making a Hydrogen-Powered Pickup for the US Army Here, the army may have an advantage. It uses JP-8 jet fuel in many of its ground vehicles and generators. For the ZH2, it could either replace supply tankers of JP-8 with tankers of H2, or, to simplify supply chains, make hydrogen from the jet fuel it’s already got.

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